Electrochemistry in Energy Applications, 4.0 credits
Electrochemistry in Energy Applications, 4.0 hp
6FITN32
Course level
Third-cycle EducationDescription
Scope and purpose
The significance of electrochemistry is only increasing due to the combination of the modern social request on use of the electricity from sustainable sources, defined in few Sustainable Development Goals of UN, and the accumulation of fundamental understanding gained in this hundred years old scientific discipline. In this perspective, the electrochemistry for green energy applications, such as batteries and green hydrogen infrastructure, are of high demand. Our course is focused on these topics.
The objective of the course is to help the students with the basic understanding of electrochemical phenomena and the orientation in this complex landscape. The course provides simplified insights of all ground-level electrode phenomena including electrode kinetics, ion transport, diffusion as well as electrode materials with emphasis of electrical energy storage.
The course structure is hybrid (physical and on-line in parallel).
Contact
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Mikhail Vagin
Course coordinator
Entry requirements
Entry requirement for studies on third-cycle education courses
- second-cycle degree,
- 240 credits in required courses, including at least 60 second-cycle credits, or
- acquisition of equivalent knowledge in some other manner
The ground knowledge of chemistry and/or solid state physics is required to enter the course.
Learning outcomes
By the end of the course the students will be able to navigate in a variety of the phenomena happening on electrodes.
Knowledge and understanding
The students will get the basic knowledge on:
the principles of direct interconversion of electrical energy to chemical energy;
the basics of the thermodynamic and kinetics of electrode reactions;
the basic operational principles of electrochemical energy devices (e.g. batteries, fuel cells and electrolyzers).
Competence and skills
The students will aquire the basic competence in electrochemical methods
Judgement and approach
The students will be able to predict the energetics of electrochemical reactions
Contents
The course provides simplified insights of all ground-level electrode phenomena including electrode kinetics, ion transport, diffusion as well as electrode materials with emphasis of electrical energy storage.
The course comprises 8 lectures of different formats + 2 discussion sessions + 2 practical sessions.
Session 1: Basics. Thermodynamics and electrochemistry
Session 2: Experimental techniques. Electrochemical experiments; electrodes; pulsed techniques; voltammetry;
Session 3: Electrode kinetics. Double layer; faradaic reactions; Tafel slopes; exchange current; standard heterogenous rate constant; overpotentials; electrocatalysis in energy conversion; mass transport limitation; hydrodynamic electrodes.
Session 4: Ionic transport and membranes. Transport of ions – general; diffusion and migration; conductivity and mobility; osmosis and electroosmosis in membranes; size and ion selectivity in membranes; nanochannel conduction phenomena; diffusion polarization; characterization and types of membranes; membrane applications.
Session 5: Discussion.
Session 6: Electrochemical devices: batteries and supercapacitors. Batteries, supercapacitor and pseudocapacitors; Ragone plot, specific capacity, specific energy, specific power, ESW; charge storage mechanism in batteries and supercapacitors; advanced rechargeable batteries: An overview.
Session 7: Electrochemical devices: fuel cells and electrolyzers. Fuel cell principles and types; fuel cell performance; principles, types and performance of hydrogen electrolyzers; redox flow batteries.
Session 8: Electrochemical impedance spectroscopy. Basics.
Session 9: Electrode materials. Carbon materials; conducting polymers; redox charge storage.
Session 10: Discussion on papers
Session 11: Experimental session: ‘half-cell’. Cyclic voltammetry; electrochemical impedance.
Session 12: Experimental session: ‘device’. Supercapacitor cell; fuel cell operation
Educational methods
Educational methods applied in this course are based on combination of classical lectures, lectures with real-time drawings, discussions and practical sessions. The four lecturers involved in the course deliver sessions with four different formats of presentation. The sessions are performed on hybride mode (physical in parallel to on-line). The materials are provided after each session.
Examination
The examination is oral in a form of real-time oral interview (physical or on-line) of each individual student cerried out by two lectures. The questions of the interview are related to the general phenomena on the electrodes. The interviews are carried out without preparation. Re-examination is possible as a repeat of the interview.
Change of examiner
Students who have failed the course or part of the course twice are entitled to request another examiner for the following examination occasion.
Course certificate
On the student’s request, course certificate is issued by the course examiner.
Grading
Two-grade scaleCourse literature
1. A. Bard, L. Faulkner. Electrochemical Methods: Fundamental and Applications. 2000, 2nd Edition, Wiley
2. Application notes of the compamies-providers of electrochemical equipment (BioLogic, Gamry, Pine, Metrohm-Autolab).
General information
The course is planned and carried out according to what is stated in this syllabus. Course evaluation, analysis and suggestions for improvement should be fed back to the Research and PhD studies Committee (FUN) by the course coordinator.